Document ...

 

Resonance Raman measurements utilizing a deep UV source

Document ID: 194

Willitsford, Adam H.¹
Chadwick, Christopher Todd²
Hallen, Hans D.²
Philbrick, C. Russell¹

¹ The Pennsylvania State University, Department of Electrical Engineering, University Park, PA, U.S.A.
² North Carolina State University, Department of Physics, Raleigh, NC, U.S.A.
 

Abstract

Raman scattering techniques have long been used as unique identifiers for spectral fingerprints of chemical and biological species. Raman lidar has been utilized on a routine basis to remotely measure several constituents in the atmosphere. While Raman scattering is very reliable in uniquely identifying molecules, it suffers from very small scattering cross sections that diminish its usefulness at increased ranges and decreased concentrations of the species of interest. By utilizing a resonance Raman technique, where the laser excitation is tuned near an electronic absorption band, it is possible to increase the Raman scattering cross section. An optical parametric oscillator (OPO) with a UV tuning range of ~220 nm – 355 nm has been utilized to explore the wavelength dependence of Raman cattering for diamond, water, benzene, and toluene. Resonance enhancements of the Raman spectra have been studied.

 

  Access pdf copy  

Keywords: resonance Raman, tunable ultraviolet laser, benzene, toluene, diamond, resonance scatter

Citation:

"Resonance Raman measurements utilizing a deep UV source", Willitsford, A. H., C. T. Chadwick, H. D. Hallen, C. R. Philbrick, Laser Radar Technology and Applications XIII, Vol. 6950, SPIE Proceedings, 2008, pp. 69500A-1 - 69500A-8, DOI: 10.1117/12.778253, CCC: 0277-786X/08